Experimental Methods for Developing Kinetic Models for Hydrocracking Reactions with Slurry-Phase Catalyst Using Batch Reactors
Experimental Methods for Developing Kinetic Models for Hydrocracking Reactions with Slurry-Phase Catalyst Using Batch Reactors
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DOI：
10.1021/acs.energyfuels.5b01953
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发表时间：
2016-05
期刊：
影响因子：
5.3
通讯作者：
Alexander Quitian;J. Ancheyta
中科院分区：
文献类型：
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作者：
Alexander Quitian;J. Ancheyta
综述了间歇操作中分散催化剂加氢裂化反应动力学的实验研究方法。讨论了反应器的批量操作条件和操作方式的描述。介绍了测定分散相催化剂加氢裂化反应化学动力学所需的实验数据的产生、分析和解释的实验方法。描述了用于此类反应研究的两种可能的间歇操作模式：等温操作和温度扫描操作。详细讨论了典型的加氢裂化动力学模型，给出了由实验数据计算化学计量系数、传质系数、速率常数和活化能的步骤。
Experimental methods for studying the chemical kinetics of hydrocracking reactions with disperse catalysts in batch operation are reviewed. Batch operating conditions and description of modes of operation of the reactors are discussed. The experimental procedures used to produce, analyze, and interpret the experimental data required for determining the chemical kinetics of hydrocracking reactions with catalyst in dispersed phase are also reviewed. Two possible batch operation modes used for the study of such reactions are described: isothermal and temperature scanning operation. The typical kinetic models for hydrocracking are discussed in detail and step-by-step procedures to calculate the stoichiometric coefficients, mass transfer coefficients, rate constants, and activation energies from experimental data are provided.