[N'-(5-Bromo-2-oxidobenzyl-idene-κO)-3-hydr-oxy-2-naphthohydrazidato-κN',O]dicyclo-hexyl-tin(IV).
[N'-(5-Bromo-2-oxidobenzyl-idene-κO)-3-hydr-oxy-2-naphthohydrazidato-κN',O]dicyclo-hexyl-tin(IV).
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[N-(5-溴-2-氧化苄基-γO)-3-羟基-2-萘甲酰肼-γN,O]二环己基锡(IV)。
DOI：
10.1107/s1600536810001145
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发表时间：
2010
期刊：
影响因子：
--
通讯作者：
Lo,KongMun
中科院分区：
文献类型：
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作者：
Lee,SeeMun;MohdAli,Hapipah;Lo,KongMun
在标题化合物[Sn(C6H11)2(C18H11BrN2O3)]中SnIV原子的环境是扭曲的三角双锥体，两个环己基和亚氮原子形成赤道面。轴向O-Sn-O角为155.97(9)°。希夫碱配体中分子内O-H⋯N氢键的存在有助于稳定整体结构。
The environment at the SnIV atom in the title compound, [Sn(C6H11)2(C18H11BrN2O3)], is distorted trigonal-bipyramidal, with the two cyclohexyl groups and the imino N atom forming the equatorial plane. The axial O—Sn—O angle is 155.97 (9)°. The presence of an intramolecular O—H⋯N hydrogen bond in the Schiff base ligand helps to stabilize the overall structure.