A convenient reagent for the conversion of aldoximes into nitriles and isonitriles.
A convenient reagent for the conversion of aldoximes into nitriles and isonitriles.
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DOI：
10.1039/d0cc00188k
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发表时间：
2020-05
影响因子：
4.9
通讯作者：
Wei Zhang;Jin‐Hong Lin;Pengfei Zhang;Ji-Chang Xiao
中科院分区：
文献类型：
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作者：
Wei Zhang;Jin‐Hong Lin;Pengfei Zhang;Ji-Chang Xiao
对于醛肟与4-硝基-1-（（三氟甲基）磺酰基）-咪唑（NTSI）的脱羟基，反应条件的轻微改变导致提供腈或异腈的显著不同的反应路径。在温和条件下实现了醛肟向异腈的具有挑战性的转化。
For the dehydroxylation of aldoximes with 4-nitro-1-((trifluoromethyl)sulfonyl)-imidazole (NTSI), slight modifications of reaction conditions resulted in significantly different reaction paths to provide either nitriles or isonitriles. The challenging conversion of aldoximes into isonitriles was achieved under mild conditions.