Thermodynamics and kinetics for the manufacture of tetrafluoroethylene by the pyrolysis of chlorodifluoromethane
Thermodynamics and kinetics for the manufacture of tetrafluoroethylene by the pyrolysis of chlorodifluoromethane
复制标题
DOI：
10.1021/ie00067a013
复制
发表时间：
1987-07
影响因子：
4.2
通讯作者：
P. Chinoy;P. D. Sunavala
中科院分区：
文献类型：
--
作者：
P. Chinoy;P. D. Sunavala
本文介绍了一氯二氟甲烷在常压下裂解的热力学和物料平衡分析，以水蒸汽为稀释剂，稀释比为0-8。用已报道的速率常数表达式导出了上述反应的速率方程，该方程是转化率和温度的函数。已报告的速率常数之一进行了校正，使热力学和动力学分析之间的良好的一致性。
This paper presents a complete thermodynamic and material balance analysis of the pyrolysis of chlorodifluoromethane at atmospheric pressure, using steam as a diluent in a diluent ratio range of 0-8. Reported expressions for the rate constants have been used to derive a rate equationfor the above reaction as a function of the conversion and temperature. One of the reported rate constants has been corrected to bring about a good consistency between the thermodynamic and kinetic analyses.