Synthesis of Nanosized TiO2 by Cationic Polymerization of (μ4-oxido)-hexakis(μ-furfuryloxo)-octakis(furfuryloxo)-tetra-titanium

Synthesis of Nanosized TiO2 by Cationic Polymerization of (μ4-oxido)-hexakis(μ-furfuryloxo)-octakis(furfuryloxo)-tetra-titanium
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DOI:
10.1002/adma.200801376
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发表时间:
2008-11-03
期刊:
影响因子:
29.4
通讯作者:
Spange, Stefan
Spange, Stefan
中科院分区:
材料科学1区
文献类型:
--
作者:
Mehner, Alexander;Rueffer, Tobias;Spange, Stefan

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通过(μ(4)-氧)六(μ-糠氧基)八(糠氧基)四钛的双聚合反应,可以合成互穿无机-有机复合材料。聚(糠醇)/二氧化钛复合材料形成,其中二氧化钛物种是均匀分散的。经热处理和水处理后,通过氧化除去复合材料的有机层,得到了纯的纳米二氧化钛(TiO 2)。
Interpenetrated inorganic-organic composite materials can be synthesized by twin polymerization Of (mu(4)-oxido)hexakis(mu-furfuryloxo)octakis(furfuryloxo)-tetra-titanium. Poly(furfuryl alcohol)/titanium dioxide composites are formed in which the titania species are uniform dispersed. Pure nanosized titanium dioxide (anatase) is obtained after heat and water treatment and removing the organic layer of the composite materials by oxidation.