Palladium on carbon encapsulated in POEPOP(1500): a resin-supported catalyst for hydrogenation reactions.
Palladium on carbon encapsulated in POEPOP(1500): a resin-supported catalyst for hydrogenation reactions.
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封装在 POEPOP(1500) 中的碳载钯：一种用于氢化反应的树脂负载催化剂。
DOI：
10.1021/ol016812x
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发表时间：
2002
期刊：
影响因子：
5.2
通讯作者：
M. Meldal
中科院分区：
文献类型：
--
作者：
A. Jansson;M. Grøtli;K. Halkes;M. Meldal
介绍了一种新型的多用途催化剂，其中碳上钯被封装在POEPOP(1500)-树脂中进行加氢反应。该聚合物负载型催化剂已成功地用于双键和三键的溶液加氢以及苯保护基团的氢解。虽然新催化剂的活性略低于标准的10% Pd/C，但它的优点是可以多次重复使用而不会显著降低反应性。
[reaction: see text] A new a versatile catalyst for hydrogenation reactions wherein palladium on carbon is encapsulated in POEPOP(1500)-resin is described. This polymer-supported catalyst has been successfully used in solution phase hydrogenation of a double and a triple bond as well as hydrogenolysis of a benzyl-protecting group. While the activity of the new catalyst is marginally lower than standard 10% Pd/C, it has the advantage of being reused several times without significant loss of reactivity.