Stable radical anions inside fullerene cages: formation of reversible electron transfer systems.
Stable radical anions inside fullerene cages: formation of reversible electron transfer systems.
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DOI：
10.1021/ja205391v
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发表时间：
2011-08
影响因子：
15
通讯作者：
T. Tsuchiya;Mateusz Wielopolski;N. Sakuma;N. Mizorogi;T. Akasaka;Tatsuhisa Kato;D. Guldi;S. Nagase-S.-Na
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文献类型：
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作者：
T. Tsuchiya;Mateusz Wielopolski;N. Sakuma;N. Mizorogi;T. Akasaka;Tatsuhisa Kato;D. Guldi;S. Nagase-S.-Na
研究了La（2）@C（80）双金属富勒烯与有机给体分子（D）在溶液中的络合行为。结果表明，La（2）@C（80）和D在基态通过电子转移相互作用形成1：1配合物。溶液中La（2）@C（80）/D和[La（2）@C（80）]（·-）/[D]（+）之间的平衡很容易通过改变温度和溶剂来控制。
The complexation behavior of La(2)@C(80) dimetallofullerenes with organic donor molecules (D) in solution has been investigated. It has been shown that La(2)@C(80) and D form 1:1 complexes as a result of electron transfer interactions in the ground state. The equilibrium between La(2)@C(80)/D and [La(2)@C(80)](•-)/[D](+) in solution is readily controlled by changing the temperature and solvent.