In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp C-H Bond.
In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp C-H Bond.
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用于快速筛选 sp C-H 键区域选择性氧化的分子识别催化剂的原位二锰催化剂。
DOI:
10.1016/j.ica.2008.06.009
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发表时间:
2009
影响因子:
2.8
通讯作者:
Crabtree,RobertH
中科院分区:
文献类型:
--
作者:
Das,Siddhartha;Brudvig,GaryW;Crabtree,RobertH
We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O2-assay study and its regioselective C–H activation activity by product analysis in catalytic runs.