A BIOTECH ROUTE TO POLYPHENYLENE
A BIOTECH ROUTE TO POLYPHENYLENE
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DOI：
10.1039/c39830000954
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发表时间：
1983-01-01
影响因子：
--
通讯作者：
TAYLOR, SC
中科院分区：
文献类型：
--
作者：
BALLARD, DGH;COURTIS, A;TAYLOR, SC
从苯和氧开始，使用遗传修饰的细菌恶臭假单胞菌作为氧化催化剂化合物（6），容易获得;后者的衍生物可溶于有机溶剂并聚合得到可溶性前体（5），其可用于制备纤维和膜，其在加热时转化为聚亚苯基纤维和膜。
Starting from benzene and oxygen and using the genetically modified bacteria Pseudominium putida as an oxidation catalyst compound (6) is readily obtained; derivative of the latter are soluble in organic solvents and polymerise to give a soluble precursor (5) which can be used to make fibres and films which on heating are converted into polyphenylene fibres and films.