Efficient 1,2-addition of aryl- and alkenylboronic acids to aldehydes catalyzed by the palladium/thioether-imidazolinium chloride system
Efficient 1,2-addition of aryl- and alkenylboronic acids to aldehydes catalyzed by the palladium/thioether-imidazolinium chloride system
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DOI：
10.1021/jo7020983
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发表时间：
2008-02-15
影响因子：
3.6
通讯作者：
Shirai, Ryuichi
中科院分区：
文献类型：
--
作者：
Kuriyama, Masami;Shimazawa, Rumiko;Shirai, Ryuichi
[图解]在钯催化的芳基、杂芳基和烯基硼酸与芳香族、杂芳族和脂肪族醛的1，2-加成反应中，以硫醚-咪唑氯化物L5作为杂二齿卡宾配体前体，可以获得高水平的催化剂性能。
[GRAPHICS]The high level of catalyst performance was attainable in the palladium-catalyzed 1,2-addition of aryl-, heteroaryl-, and alkenylboronic acids to aromatic, heteroaromatic, and aliphatic aldehydes using thioether-imidazolinium chloride L5 as a heterobidentate carbene ligand precursor.