Soft chemical control of the crystal and magnetic structure of a layered mixed valent manganite oxide sulfide
Soft chemical control of the crystal and magnetic structure of a layered mixed valent manganite oxide sulfide
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DOI：
10.1063/1.4918973
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发表时间：
2015-04-01
期刊：
影响因子：
6.1
通讯作者：
Clarke, Simon J.
中科院分区：
文献类型：
--
作者：
Blandy, Jack N.;Abakumov, Artem M.;Clarke, Simon J.
铜离子从层状混合价锰氧化物硫化物Sr2MnO2Cu1.5S2的硫化物层的氧化脱嵌导致控制铜空位调制的超结构和由锰离子携带的磁矩的有序排列。这种软化学能够控制这些复合材料的结构和性质，这些复合材料补充了混合价钙钛矿和钙钛矿相关的过渡金属氧化物。(C)2015年作者。
Oxidative deintercalation of copper ions from the sulfide layers of the layered mixed-valent manganite oxide sulfide Sr2MnO2Cu1.5S2 results in control of the copper-vacancy modulated superstructure and the ordered arrangement of magnetic moments carried by the manganese ions. This soft chemistry enables control of the structures and properties of these complex materials which complement mixed-valent perovskite and perovskite-related transition metal oxides. (C) 2015 Author(s).