Single-component, low molecular weight organic supergelators based on chiral barbiturate scaffolds
Single-component, low molecular weight organic supergelators based on chiral barbiturate scaffolds
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DOI：
10.1080/10610278.2019.1629437
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发表时间：
2019-06
影响因子：
3.3
通讯作者：
Daniel T. Seidenkranz;K. Langworthy;L. Zakharov;Michael D. Pluth
中科院分区：
文献类型：
--
作者：
Daniel T. Seidenkranz;K. Langworthy;L. Zakharov;Michael D. Pluth
摘要本文报道了第一个手性巴比妥酸盐作为单组分LMOG，能够凝胶化各种氯化和芳香族溶剂。基于溶液的DOSY NMR实验，固态VP-SEM，和X-射线晶体学技术被用来表征氯仿为基础的凝胶在各种尺寸域。这种支架提供了一个简单的系统来研究凝胶化和自组装的动力学。图形摘要
ABSTRACT We report here the first chiral barbiturate to act as a single-component LMOG capable of gelating a variety of chlorinated and aromatic solvents. Solution-based DOSY NMR experiments, solid-state VP-SEM, and X-ray crystallography techniques were used to characterize chloroform-based gels at a variety of size domains. This scaffold provides a simple system to study the dynamics of gelation and self-assembly. Graphical abstract