CHAPTER 4:Healable Supramolecular Polymeric Materials
CHAPTER 4:Healable Supramolecular Polymeric Materials
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第 4 章：可修复超分子聚合物材料
DOI：
10.1039/9781849737470-00092
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发表时间：
2013
影响因子：
2.5
通讯作者：
C. Weder
中科院分区：
文献类型：
--
作者：
B. W. Greenland;Gina L. Fiore;S. Rowan;C. Weder
本章详细介绍了设计，合成和评估技术需要生产愈合的超分子材料。概述了超分子聚合物化学的主要发展，这些发展奠定了生产响应性材料所必需的设计概念。随后，从文献中选择的例子有关的合成和分析的可愈合的材料含有氢键，π-π堆积和金属配体相互作用进行评估。最后一节介绍了最近的努力，以生产可愈合的凝胶利基应用，包括电解质和组织工程支架。本章还描述了纳米复合材料的设计标准和生产，与前几代超分子材料相比，纳米复合材料的强度显著增加，同时仍保留了关键的愈合特性。
This chapter details the design, synthesis and evaluation techniques required to produce healable supramolecular materials. Key developments in supramolecular polymer chemistry that laid down the design concepts necessary to produce responsive materials are summarized. Subsequently, select examples from the literature concerning the synthesis and analysis of healable materials containing hydrogen bonding, π−π stacking and metal–ligand interactions are evaluated. The last section describes the most recent efforts to produce healable gels for niche applications, including electrolytes and tissue engineering scaffolds. The chapter also describes the design criteria and production of nano-composite materials that exhibit dramatically increased strength compared to previous generations of supramolecular materials, whilst still retaining the key healing characteristics.