The synthesis and structural characterization of the technetium nitrosyl complexes [TcCl(NO)(SC5H4N)(PPh3)2] and [Tc(NO)(SC5H4N)2(PPh3)].
The synthesis and structural characterization of the technetium nitrosyl complexes [TcCl(NO)(SC5H4N)(PPh3)2] and [Tc(NO)(SC5H4N)2(PPh3)].
复制标题
亚硝酰基锝络合物[TcCl(NO)(SC5H4N)(PPh3)2]和[Tc(NO)(SC5H4N)2(PPh3)]的合成和结构表征。
DOI：
10.1016/j.ica.2010.09.025
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发表时间：
2011
影响因子：
2.8
通讯作者：
Jones,AlunG
中科院分区：
文献类型：
--
作者：
Nicholson,TerrenceL;Mahmood,Ashfaq;Muller,Peter;Davison,Alan;Storm-Blanchard,Shannon;Jones,AlunG
The reaction of the Tc(I) complex [Tc(NO)Cl2(HOMe)(PPh3)2] with stoichiometric amounts of 2-mercatopyridine and a proton scavenger yields [Tc(NO)Cl(Spy)(PPh3)2] or [Tc(NO)(Spy)2(PPh3)], depending upon quantities of ligands employed. These two complexes have been structurally characterized. The small bite angles of the bidentate mercaptopyridine ligands cause significant deviation from octahedral coordination geometry.
