Modulation of Homochiral DyIII Complexes: Single-Molecule Magnets with Ferroelectric Properties
Modulation of Homochiral DyIII Complexes: Single-Molecule Magnets with Ferroelectric Properties
复制标题
同手性 DyIII 配合物的调制:具有铁电特性的单分子磁体
DOI:
10.1002/chem.201201190
复制
发表时间:
2012-11-01
影响因子:
4.3
通讯作者:
Fang, Shao-Ming
中科院分区:
文献类型:
--
作者:
Li, Xi-Li;Chen, Chun-Lai;Fang, Shao-Ming
Homochiral Dy (III) complexes: by changing the ligand-to-metal ratio, enantiomeric pairs of a Dy (III) complex of different nuclearity could be obtained. The mono-and dinuclear complexes exhibit characteristics of single-molecule magnets and different slow magnetic relaxation processes. In addition, the dinuclear complexes exhibit ferroelectric behavior, thus representing the first chiral polynuclear lanthanide-based single-molecule magnets with ferroelectric properties.