Scalable Flow Synthesis of [6,6]-Phenyl-C61-Butyric Acid Methyl Ester (PCBM) using a Flow Photoreactor with a Sodium Lamp
Scalable Flow Synthesis of [6,6]-Phenyl-C61-Butyric Acid Methyl Ester (PCBM) using a Flow Photoreactor with a Sodium Lamp
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使用带有钠灯的流动光反应器可扩展流动合成 [6,6]-苯基-C61-丁酸甲酯 (PCBM)
DOI：
10.1002/ejoc.201700745
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
I.
中科院分区：
文献类型：
--
作者：
Ueda;M.; Imai;N.; Yoshida;S.; *Yasuda;H.; *Fukuyama;T.; Ryu;I.
构建了一个高效的流动系统来合成[6，6]-苯基-C61-丁酸甲酯（PCBM）;该过程包括C60的[2+1]流动添加，然后通过使用流动光反应器将所得的富勒烯流动光异构化为PCBM。与钠灯相结合。利用本流动系统，通过连续操作3.3 h实现了PCBM（0.79 g/3.3 h）的可放大合成。
An efficient flow system was constructed for the synthesis of [6,6]‐phenyl‐C61‐butyric acid methyl ester (PCBM); the process involved flow [2+1] addition of C60and subsequent flow photoisomerization of the resulting fulleroid to PCBM by using a flow photoreactor in combination with an Na lamp. With the present flow system, a scalable synthesis of PCBM (0.79 g/3.3 h) was achieved by continuous operation for 3.3 h.