Hydrophilic nature of silicate glass surfaces as a function of exposure condition
Hydrophilic nature of silicate glass surfaces as a function of exposure condition
复制标题
DOI：
10.1016/j.jnoncrysol.2003.08.078
复制
发表时间：
2003-12-01
影响因子：
3.5
通讯作者：
Shelby, JE
中科院分区：
文献类型：
--
作者：
DeRosa, RL;Schader, PA;Shelby, JE
该工作比较了熔融石英、BK-7 和苏打硅酸盐 (SLS) 玻璃表面的亲水性随暴露条件的变化。使用氧（O-2）等离子体、水（H2O）等离子体和水性环境（UV/H2O）中的紫外线（UV）辐射（340 nm，0.4 W/m(2)）的组合处理作为曝光处理。 The hydrophilic character of the surfaces was based on Fourier transform infrared reflectance studies (4000-3000 cm(-1) region) and contact angle analysis.结果发现，SLS 玻璃同样受到所有三种曝光条件的影响，至少对红外反射分析的穿透深度（与法线成 84 度）影响如此。使用 UV/H2O 处理或 H2O 等离子体处理，熔融石英和 BK-7 实现了更亲水的行为。红外分析证实，熔融石英和BK-7玻璃经O-2等离子体处理后，表面产生了游离的硅烷醇基团，导致处理后亲水性降低。 (C) 2003 Elsevier B.V. 保留所有权利。
The work presented compares the hydrophilic nature of fused silica, BK-7 and soda time silicate (SLS) glass surfaces as a function of exposure conditions. Oxygen (O-2) plasma, water (H2O) plasma and a combination treatment of ultraviolet (UV) radiation (340 nm, 0.4 W/m(2)) in an aqueous environment (UV/HO) were used as the exposure treatments. The hydrophilic character of the surfaces was based on Fourier transform infrared reflectance studies (4000-3000 cm(-1) region) and contact angle analysis. It was found that the SLS glass was equally affected by all three exposure conditions, at least to the penetration depth of the IR reflection analysis (84degrees to the normal). A more hydrophilic behavior was achieved for fused silica and BK-7 using either the UV/H2O treatment or the H2O plasma treatment. It was confirmed by IR analysis that the O-2 plasma treatment of fused silica and BK-7 glass resulted in free silanol groups at the surface, which contributed to the lower hydrophilicity after treatment. (C) 2003 Elsevier B.V. All rights reserved.