Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate.
Transition metal decorated soft nanomaterials through modular self-assembly of an asymmetric hybrid polyoxometalate.
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DOI：
10.1039/d0cc03554h
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发表时间：
2020-06
影响因子：
4.9
通讯作者：
Elizabeth Hampson;Jamie M. Cameron;J. Watts;Graham N. Newton
中科院分区：
文献类型：
--
作者：
Elizabeth Hampson;Jamie M. Cameron;J. Watts;Graham N. Newton
一个不对称的功能化韦尔斯-道森有机-无机杂化聚氧乙烯酸已后功能化的Pt 2+配位，并展示了自组装成表面修饰的胶束纳米结构。这种多功能杂化材料被发现是一种氧化还原活性的软纳米材料，并展示了一种新的分子设计策略，具有在光催化或电催化中应用的潜力。
An asymmetrically functionalised Wells-Dawson organic-inorganic hybrid polyoxometalate has been post-functionalised by Pt2+ coordination, and demonstrates self-assembly into surface-decorated micellar nanostructures. This multifunctional hybrid material is found to be a redox-active soft nanomaterial and demonstrates a new molecular design strategy with potential for applications in photo- or electro-catalysis.