A light-through-side cell and co-used furnace designed for micro-Raman spectra study on volatile melts
A light-through-side cell and co-used furnace designed for micro-Raman spectra study on volatile melts
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专为挥发性熔体的显微拉曼光谱研究而设计的透光侧池和共用炉
DOI：
10.1016/j.cclet.2012.10.004
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发表时间：
2012-11
影响因子：
9.1
通讯作者：
王兆文
中科院分区：
文献类型：
--
作者：
胡宪伟;李欢;高炳亮;刘敬敬;石忠宁;于江玉;王兆文
介绍了一种专门用于挥发性熔体微拉曼光谱研究的新型样品池。电池是由石英制成的。所述电池下部为圆形环状，电池内的一端封闭孔用于定位发热体。将连接在细胞盖上的用于放置热电偶的管插入样品中，确保了温度测量精度良好。电池可以密封，以减少由不均匀挥发引起的成分变化的影响。在拉曼光谱扫描过程中，激光束通过侧面而不是顶部进入细胞。同时，设计了一个与电池相匹配的熔炉。加热体与样品池紧密耦合，炉侧壁上有微透镜入口孔。该组件在602°C的熔融纳米3的拉曼光谱测试中表现良好。
A new type of sample cell specially designed for micro-Raman spectra study on volatile melts is described. The cell is made of quartz. The lower section of the cell is circular ring-shaped and the one-end-closed hole in the cell is used for locating the heating body. The tube attached to the cell lid for placing the thermal couple is inserted into the sample, which ensures that the temperature measurement accuracy is good. The cell can be sealed for reducing the effect of the composition change caused by the inhomogeneous volatilization. During the Raman spectra scanning, the laser beam is transmitted into the cell through the side but not the top. Meanwhile, a furnace has been designed to match the cell. The heating body is closely coupled with the sample cell, and there is a hole on the side wall of the furnace for the entrance of the microlens. The assembly has performed well in the tested Raman spectrum measurement of molten NaNO3at 602°C.
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DOI：
10.1039/b111563b
发表时间：
2002-01-01
期刊：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
影响因子：
--
作者：
Stefanidaki, E;Photiadis, GM;Ostvold, T
通讯作者：
Ostvold, T
影响因子：
7.4
作者：
J. P. Young
通讯作者：
J. P. Young
DOI：
10.1039/a802812e
发表时间：
1998
期刊：
Journal of the Chemical Society, Faraday Transactions
影响因子：
--
作者：
V. Dracopoulos;B. Gilbert;G. Papatheodorou
通讯作者：
V. Dracopoulos;B. Gilbert;G. Papatheodorou
影响因子：
3.5
作者：
B. Gilbert;G. Mamantov;G. Begun
通讯作者：
B. Gilbert;G. Mamantov;G. Begun
DOI：
--
发表时间：
2010
期刊：
--
影响因子：
--
作者：
enat R. Nazmutdinova;Tamara T. Zinkichevaa;Sergey Yu. Vassilievb;V. Glukhova;G. A. Tsirlinab;Michael Probst
通讯作者：
enat R. Nazmutdinova;Tamara T. Zinkichevaa;Sergey Yu. Vassilievb;V. Glukhova;G. A. Tsirlinab;Michael Probst