Highly Enantioselective [3+2] Cycloaddition of Vinylcyclopropane with Nitroalkenes Catalyzed by Palladium(0) with a Chiral Bis(tert-amine) Ligand
Highly Enantioselective [3+2] Cycloaddition of Vinylcyclopropane with Nitroalkenes Catalyzed by Palladium(0) with a Chiral Bis(tert-amine) Ligand
复制标题
高对映选择性 [3 2] 手性双（叔胺）配体钯 (0) 催化乙烯基环丙烷与硝基烯烃的环加成反应
DOI：
10.1002/chem.201405407
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发表时间：
2015-02-02
影响因子：
4.3
通讯作者：
Liu, Li
中科院分区：
文献类型：
--
作者：
Wei, Feng;Ren, Chuan-Li;Liu, Li
由 1,3-茚满二酮衍生的乙烯基环丙烷与硝基烯烃在钯 (0) 催化下与手性双（叔胺）配体进行对映选择性 [3+2] 环加成反应，具有良好的非对映选择性和优异的对映选择性，收率高。所得双（叔胺）-钯络合物被证明是该环加成的高效催化剂。
An enantioselective [3+2] cycloaddition of vinyl cyclopropane derived from 1,3-indanedione with nitroalkenes catalyzed by palladium(0) with a chiral bis(tert-amine) ligand was developed in high yields with good diastereoselectivities and excellent enantioselectivities. The resulting bis(tert-amine)-palladium complex proved to be a highly efficient catalyst for this cycloaddition.