Correction to “Thermodynamic Analysis of Metal–Ligand Cooperativity of PNP Ru Complexes: Implications for CO 2 Hydrogenation to Methanol and Catalyst Inhibition”
Correction to “Thermodynamic Analysis of Metal–Ligand Cooperativity of PNP Ru Complexes: Implications for CO 2 Hydrogenation to Methanol and Catalyst Inhibition”
复制标题
对“金属热力学分析”PNP Ru 配合物的配体协同性的修正：对 CO 2 加氢生成甲醇和催化剂抑制的影响
DOI：
10.1021/jacs.1c06789
复制
发表时间：
2021
影响因子：
15
通讯作者：
Saouma, Caroline T.
中科院分区：
文献类型：
--
作者：
Mathis, Cheryl L.;Geary, Jackson;Ardon, Yotam;Reese, Maxwell S.;Philliber, Mallory A.;VanderLinden, Ryan T.;Saouma, Caroline T.
支持信息中的公式13包含符号错误，导致报告的（PNP）Ru− CO2和PNP的pKa值不正确。（PNP）Ru− CO2的pKa应为26.1±0.4（不是24.6±0.4）。PNP的pKa应为29.0±0.4（而非28.6±0.4）。在第14322页左列最后一段（PNP）和右列第一段（（PNP）Ru− CO2）、第14323页表2以及SI（表S3和图S12标题）中报告了相同的错误pKa值。
Equation 13 in the Supporting Information contained a sign error, resulting in the incorrect pKa values reported for (PNP) Ru− CO2 and PNP. The pKa of (PNP) Ru− CO2 should be 26.1±0.4 (not 24.6±0.4). The pKa of PNP should be 29.0±0.4 (not 28.6±0.4).The same incorrect pKa values are reported on page 14322, in the left column, last paragraph for PNP, and in the right column, first paragraph for (PNP) Ru− CO2), and on page 14323, in Table 2, as well as in the SI (Table S3 and Figure S12 caption).