Metallic Catalysts for Oxidative Dehydrogenation of Propane Using CO <sub>2</sub>
Metallic Catalysts for Oxidative Dehydrogenation of Propane Using CO <sub>2</sub>
复制标题
使用 CO <sub>2</sub> 进行丙烷氧化脱氢的金属催化剂
DOI：
10.1002/chem.202202173
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发表时间：
2022
期刊：
影响因子：
--
通讯作者：
Furukawa Shinya
中科院分区：
文献类型：
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作者：
Xing Feilong;Furukawa Shinya
使用 CO2(CO2−ODP) 进行丙烷氧化脱氢是实现高产丙烯生产和 CO2 使用的一种有前景的技术。开发高效的 CO2−ODP 催化剂对于化学工业和实现净零排放至关重要且有益。许多研究研究了金属氧化物基催化剂，表明快速失活和低选择性仍然是其工业应用的限制因素。近年来，金属纳米粒子催化剂因其独特的性能而变得越来越有吸引力。因此，我们通过考虑催化剂设计概念、反应过程中的不同机制以及CO2的作用，总结了金属基催化剂在CO2−ODP反应中的性能。
The oxidative dehydrogenation of propane using CO2(CO2−ODP) is a promising technique for realizing high‐yield propylene production and CO2usage. Developing a highly efficient catalyst for CO2−ODP is essential and beneficial to the chemical industry and for realizing net‐zero emissions. Many studies have investigated metal oxide‐based catalysts, revealing that rapid deactivation and low selectivity remain limiting factors for their industrial applications. In recent years, metallic nanoparticle catalysts have become increasingly attractive due to their unique properties. Therefore, we summarize the performance of metal‐based catalysts in CO2−ODP reactions by considering catalyst design concepts, different mechanisms in the reaction process, and the role of CO2.