Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution.
Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution.
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DOI：
10.1039/c4cc00537f
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发表时间：
2014-03
影响因子：
4.9
通讯作者：
Teresa M. Eaton;Jian Lin;J. Cross;J. Stritzinger;T. Albrecht‐Schmitt
中科院分区：
文献类型：
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作者：
Teresa M. Eaton;Jian Lin;J. Cross;J. Stritzinger;T. Albrecht‐Schmitt
合成并表征了Th(VO_3)_2(SeO_3)和Ln(VO_3)_2(IO_3)(Ln=Ce、Pr、Nd、Sm和Eu)。令人惊讶的是，这些化合物是同型的，并且在这种结构类型中可能存在相当极端的异价取代例子(Th(IV)与Ln(III)；Se(IV)O_3(2-)与I(V)O_3(-))。
Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (Th(IV)vs. Ln(III); Se(IV)O3(2-)vs. I(V)O3(-)) are possible in this structure type.