Core-shell structured microcapsular-like Ru@SiO2 reactor for efficient generation of CO(x)-free hydrogen through ammonia decomposition.
Core-shell structured microcapsular-like Ru@SiO2 reactor for efficient generation of CO(x)-free hydrogen through ammonia decomposition.
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DOI：
10.1039/c0cc00430h
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发表时间：
2010-07
影响因子：
4.9
通讯作者：
Yanxing Li;Lianghong Yao;Yanyan Song;Shunqiang Liu;J. Zhao;W. Ji;C. Au
中科院分区：
文献类型：
--
作者：
Yanxing Li;Lianghong Yao;Yanyan Song;Shunqiang Liu;J. Zhao;W. Ji;C. Au
核壳结构的微胶囊状Ru@SiO(2)反应器被证明是迄今为止已知的通过氨分解生产无CO(x)氢用于燃料电池应用的最有效的材料。由于惰性 SiO(2) 纳米壳的保护，非常活跃的 Ru 核颗粒即使在高温（高达 650 摄氏度）下也能保持良好的稳定性。
The core-shell structured microcapsular-like Ru@SiO(2) reactor is proved to be the most efficient material known to date for CO(x)-free hydrogen production via ammonia decomposition for fuel cells application. The very active Ru core particles can retain good stability even at high temperatures (up to 650 degrees C) thanks to the protection of the inert SiO(2) nano-shell.