Characterization of BaSnO3-based ceramics -: Part 1.: Synthesis, processing and microstructural development
Characterization of BaSnO3-based ceramics -: Part 1.: Synthesis, processing and microstructural development
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DOI：
10.1016/s0925-8388(98)00370-3
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发表时间：
1998-05-29
影响因子：
6.2
通讯作者：
Hon, NC
中科院分区：
文献类型：
--
作者：
Azad, AM;Hon, NC
化合物BaSnO 3及其Ca-和Sr-类似物最近被预测为潜在的电子陶瓷材料（热稳定电容器、湿度、CO和NO的化学传感器等）。为了填补研究报告中的信息空白，对这些外来材料进行了积极而系统的调查。本文对BaSnO_3的合成、加工和微观结构进行了深入的研究。为了建立一个标准的方法，低成本的大规模生产具有相同的和有益的微观结构和可再现的电气特性，不同的合成路线（固态和自热持续）被采用。微观结构的演变，这是密切相关的陶瓷中的设想的性能，密切和系统地遵循在很宽的温度范围内的烧结和浸泡时间。该通信形式的第一个两个部分在一系列的调查MSnO 3，系统，其中结果的合成和加工的“相纯”锡酸钡（BaSnO 3）和有趣的微观结构的发展。(C)1998年Elsevier Science S.A.
The compound BaSnO3, together with its Ca- and Sr-analogs, has recently been projected as potential electronic ceramic material (thermally stable capacitor, chemical sensor for humidity, CO and NO,, etc.). In order to fill the information gaps in the reported research, a vigorous and systematic investigation on these exotic materials has been initiated. A thorough study of BaSnO3, with respect to its synthesis, processing and microstructural characterization has been made. In order to establish a standard methodology for low-cost mass-manufacturing with identical and beneficial microstructure and reproducible electrical characteristics, different synthesis routes (solid-state and self-heat-sustained) were adopted. Evolution of microstructure which is intimately related to the envisaged properties in the ceramics, was closely and systematically followed in terms of sintering over a wide range of temperatures and soak time. This communication forms the first of two parts in a series of investigations on MSnO3, systems, where results on the synthesis and processing of "phase pure" barium stannate (BaSnO3) and development of interesting microstructure are presented. (C) 1998 Elsevier Science S.A.