Metal–Organic Frameworks with Low‐Valent Metal Nodes
Metal–Organic Frameworks with Low‐Valent Metal Nodes
复制标题
具有低价金属节点的金属有机框架
DOI：
10.1002/anie.202206353
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发表时间：
2022
期刊：
影响因子：
--
通讯作者：
Cohen, Seth M.
中科院分区：
文献类型：
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作者：
Sikma, R. Eric;Balto, Krista P.;Figueroa, Joshua S.;Cohen, Seth M.
金属有机骨架（MOFs）是由金属和多位有机配体之间的键合相互作用形成的结晶的二维和三维配位聚合物。这些通常使用具有高氧化态金属离子的硬刘易斯碱性有机配体形成。在MOF中使用低价金属作为结构元素远不常见，尽管这些金属广泛用于催化，发光和其他应用。这篇小综述重点介绍了低价MOFs领域的最新进展，并对这些材料的未来发展提供了展望。
Metal–organic frameworks (MOFs) are crystalline, 2‐ and 3‐dimensional coordination polymers formed by bonding interactions between metals and multitopic organic ligands. These are typically formed using hard Lewis basic organic ligands with high oxidation state metal ions. The use of low‐valent metals as structural elements in MOFs is far less common, despite the widespread use of such metals for catalysis, luminescence, and other applications. This Minireview focuses on recent advances in the field of low‐valent MOFs and offers a perspective on the future development of these materials.