Synthesis of Different Classes of Six-Membered Gold(I) NHC Complexes by the Isonitrile Route
Synthesis of Different Classes of Six-Membered Gold(I) NHC Complexes by the Isonitrile Route
复制标题
异腈路线合成不同类别的六元金(I) NHC配合物
DOI：
10.1021/acs.organomet.6b00023
复制
发表时间：
2016
期刊：
影响因子：
2.8
通讯作者：
A. Hashmi
中科院分区：
文献类型：
--
作者：
T. Wurm;Florian F. Mulks;Constantin R. N. Böhling;Dominic Riedel;Poorya Zargaran;M. Rudolph;F. Rominger;A. Hashmi
以异腈金配合物为前体，通过与适当官能化的胺结合，制备了不同类型的六元N-杂环金卡宾配合物。这些简单的方法不仅可以方便地合成不对称取代的饱和卡宾配合物，而且还可以合成六元N-杂环氧代卡宾配合物等罕见的卡宾配合物，并可以合成六元部分不饱和配体。
Different types of six-membered N-heterocyclic gold carbene complexes were prepared by using gold(I) isonitrile complexes as precursors in combination with suitably functionalized amines. The simple procedures provide an easy access to not only unsymmetrically substituted saturated carbene complexes but rarely reported types of carbene complexes such as six-membered N-heterocyclic oxo-carbene complexes, and six-membered partly unsaturated ligands can be obtained following the strategy.
影响因子：
3.6
作者：
Jazzar, Rodolphe;Bourg, Jean-Baptiste;Bertrand, Guy
通讯作者：
Bertrand, Guy