High bromine oxide concentrations in the semi-polluted boundary layer
High bromine oxide concentrations in the semi-polluted boundary layer
复制标题
半污染边界层中溴氧化物浓度较高
DOI：
10.1016/j.atmosenv.2009.05.033
复制
发表时间：
2009
影响因子：
5
通讯作者：
J. Plane
中科院分区：
文献类型：
--
作者：
A. Mahajan;H. Oetjen;James D. Lee;A. Saiz‐Lopez;G. Mcfiggans;J. Plane
Bromine chemistry in the marine boundary layer is recognized to play an important role through catalytic ozone destruction, changes to the atmospheric oxidising capacity (by changing the OH/HO2and NO/NO2ratio) and oxidation of compounds such as dimethyl sulphide (DMS). However, the chemistry of bromine in polluted environments is not well understood and its effects are thought to be inhibited by reactions involving NOx(NO2& NO). This paper describes long-path Differential Optical Absorption Spectroscopy (DOAS) observations of bromine oxide (BrO) at a semi-polluted coastal site in Roscoff, France. Significant concentrations of BrO (up to 7.5 ± 1.0 pptv) were measured during daytime, indicating the presence of unknown sources or efficient recycling of reactive bromine from bromine nitrate (BrONO2), which should be the major reservoir for bromine in a high NOxenvironment. These measurements indicate that bromine chemistry can play an important role in polluted environments.
影响因子：
64.8
作者：
Read, Katie A.;Mahajan, Anoop S.;Plane, John M. C.
通讯作者：
Plane, John M. C.
碘介导的沿海颗粒形成：海洋边界层中的活性卤素 (RHaMBLe) 概述 Roscoff 沿海研究
DOI：
10.5194/acpd-9-26421-2009
发表时间：
2009
期刊：
--
影响因子：
--
作者：
McFiggans G
通讯作者：
McFiggans G