Amide-Directed Bay-Region Two-Step Annulative pi-Extension (APEX) of Biphenyls and Terphenyls with Diaryliodonium Salts: Efficient Access to Polycyclic Aromatic Hydrocarbons
Amide-Directed Bay-Region Two-Step Annulative pi-Extension (APEX) of Biphenyls and Terphenyls with Diaryliodonium Salts: Efficient Access to Polycyclic Aromatic Hydrocarbons
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联苯和三联苯与二芳基碘鎓盐的酰胺导向湾区两步环形 pi 延伸 (APEX)：有效获取多环芳烃
DOI：
10.1002/adsc.201901010
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发表时间：
2020
影响因子：
5.4
通讯作者：
Xiang Shi-Kai
中科院分区：
文献类型：
--
作者：
Peng Qiong;Zhang Wen;Zhao Ke;Du Yu;Feng Chun;Wang Bi-Qin;Fang Dong-Mei;Chen Xiao-Zhen;Ni Hai-Liang;Xiang Shi-Kai
本文报道了联苯和三联苯与二芳基碘鎓盐的酰胺导向bay区两步环化π-延伸反应。根据该方法可以有效地合成各种多环芳烃，例如苯并菲、二苯并[fg，op]并四苯和三苯并[fg，ij，rst]并五苯衍生物。
An amide‐directed bay‐region two‐step annulative π‐extension reaction of biphenyls and terphenyls with diaryliodonium salts has been developed. A variety of polycyclic aromatic hydrocarbons can be synthesized efficiently according to this approach, such as triphenylene, dibenzo[fg,op]tetracene, and tribenzo[fg,ij,rst]pentaphene derivatives.