Substituent groups-driven construction of two different Cd(II) coordination polymers from CdSO4, tetrakis(4-pyridyl)cyclobutane and 5-R-1,3-benzenedicarboxylates
Substituent groups-driven construction of two different Cd(II) coordination polymers from CdSO4, tetrakis(4-pyridyl)cyclobutane and 5-R-1,3-benzenedicarboxylates
复制标题
由 CdSO4、四(4-吡啶基)环丁烷和 5-R-1,3-苯二甲酸酯取代基驱动构建两种不同的 Cd(II) 配位聚合物
DOI：
10.1016/j.inoche.2013.07.014
复制
发表时间：
2013-09-01
影响因子：
3.8
通讯作者：
Lang, Jian-Ping
中科院分区：
文献类型：
--
作者：
Li, Duan-Xiu;Chen, Min-Min;Lang, Jian-Ping
Hydrothermal reactions of CdSO4 with tetrakis(4-pyridyl)cyclobutane (tpcb) and 1,3-benzenedicarboxylic acid (1,3-H2BDC) or 5-nitro-1,3-benzenedicarboxylic acid (5-NO2-1,3-H2BDC) resulted in the formation of two coordination polymers [Cd(tpcb)(0.5)(1,3-BDC](n) (1) and {[Cd-2(tpcb)(5-NO2-1,3-BDC)(2)(OH2)(2)] center dot 4H(2)O}n (2), respectively. Compounds 1 and 2 were characterized by elemental analysis, IR, powder X-ray diffraction, and single-crystal X-ray diffraction. 1 and 2 exhibit two different types of two-fold interpenetrating 3D architectures with (6(6))(2)(6(4)center dot 8(2)) and (5(2)center dot 8)(5(4)center dot 6 center dot 8)(4 center dot 5(3) center dot 6(2) center dot 7 center dot 8(2) center dot 10) Schlafli symbols, respectively. Their thermal and photoluminescent properties were also investigated. (C) 2013 Elsevier B.V. All rights reserved.
