Molecular theory of gases and liquids
Molecular theory of gases and liquids
复制标题
DOI：
10.1021/ed032p232.2
复制
发表时间：
1955-04
影响因子：
3
通讯作者：
R. Scott
中科院分区：
文献类型：
--
作者：
R. Scott
这是二十年来第一本关于有机化学问题的书。大多数基础有机化学教师都认为，对于学生来说，要让新的语言和有机化学的无数细节成为自己的一部分，并意识到有机化合物类别的相互关系，没有比解决许多不同类型的问题更好的方法了。这本书包含 29 章、一个答案部分、一个“名字”反应列表、参考文献和一个足够的索引。前 28 章按照大多数有机教科书的经典顺序按照有机化合物的类别排列。每一章的开头都是对命名法的精彩系统讨论，强调 IU C.，但也包括其他系统和通用名称。然后简要概述了所处理化合物类别的制备方法、物理性质和反应，并提出了一系列问题。这些问题说明（I）有机化合物的命名；（2）从名称中写出公式；（3）制备方法；（4）合成；（5）通过一种简单的方法平衡氧化还原方程，该方法将理论上氧化化合物的一个分子所需的氧原子数的电子变化等于所用特定氧化剂的电子变化；（6）从定量和定性数据确定结构，需要回顾无机、定性和化学物质的计算。定量化学；（7）有机化合物的区分方法； （8）科学的一些理论方面。第29章包含80个不同难度的识别或结构问题。所有问题都在第 29 章之后的答案部分得到了简洁的回答。每个答案都给出了足够的解释，使学生能够清楚地理解作者的推理，并相应地编辑自己的推理。有些问题的答案仅取决于本书中包含的材料，但为了解决许多问题，学生被迫参考自己的教科书和其他教科书、物理常数表以及其他参考书。索引前面的“名称”反应列表在这方面是一个有用的指南。
This is the first book of problems in organic chemistry in twenty years or more. Most teachers of elementary organic chemistry agree that there is no better way for a student to make the new language andmyriad details of organic chemistry a part of himself andto become aware of the interrelationship of classes of organic compounds than to solve many and different types of problems. The book contains 29 chapters, an answer section, a list of “name” reactions, references, and an adequate index. The first 28 chapters are arranged according to classes of organic com-pounds in the classical order of most organic textbooks. Each chapter is headed by an excellent systematic discussion of nomen-clature stressing the IU C. but including also other systems and common names. Then a short outline of the methods of preparation, physical properties, and reactions of the class of compounds under treatment is presented and followedby a series of problems. These problems illustrate (I) naming of organic compounds;(2) writing formulas from names;(3) preparative methods;(4) syntheses;(5) balancing of oxidation-reduction equations by a simple method of equating the electron change for the number of oxygen atoms theoretically necessary to ox-idize one molecule of the compound to the electron change of the specific oxidizing agent used;(6) determination of structure from quantitative and qualitative data entailing a review of the cal-culations of inorganic, qualitative, and quantitative chemistry;(7) methods ofdistinguishing organic compounds; and (8) some of the theoretical aspects of the science. Chapter 29 consists of 80 identification or structure problems of varying degrees of difficulty. Allof the problems are answered concisely in an answer section following Chapter 29. Enough explanation is given in each answer to enable the student to follow clearly the reasoning of the authors and to edit his own accordingly. The answers to some of the problems depend only on material included in this book, but to solve many of the problems the student, is forced to refer to his own and other textbooks, to tables of physical constants, and to other reference books. The “name” reactions list which precedes the index is a helpful guide in this connection.