Slip to π Ru: structural distortions due to metal-iminoxolene π bonding
Slip to π Ru: structural distortions due to metal-iminoxolene π bonding
复制标题
滑向 Ï Ru：金属-亚氨基氧戊二烯 Ï 键合导致结构扭曲
DOI：
10.1039/d3cc02943c
复制
发表时间：
2023
影响因子：
4.9
通讯作者：
Brown, Seth N.
中科院分区：
文献类型：
--
作者：
Ayson, Patricia Rose;Brown, Seth N.
伪八面体和伪方锥双亚胺氧杂环戊烯配合物反式-(Diso)2RuCl2和反式-(Diso)2Ru(PPh3)在结构上都发生了扭曲，钌原子从理想化配位多面体的双轴上滑落。发生这些扭曲是因为它们允许或增强钌和亚氨基氧杂环戊烯 π 轨道之间的 π 相互作用。
Both pseudo-octahedral and pseudo-square pyramidal bis-iminoxolene complexes trans-(Diso)2RuCl2 and trans-(Diso)2Ru(PPh3) are structurally distorted, with the ruthenium atom slipping off the twofold axis of the idealized coordination polyhedra. These distortions take place because they allow or enhance π interactions between ruthenium and the iminoxolene π orbitals.