Surplus adsorption of bromide ion into π-conjugated carbon nanospaces assisted by proton coadsorption
Surplus adsorption of bromide ion into π-conjugated carbon nanospaces assisted by proton coadsorption
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DOI：
10.1016/j.jcis.2017.08.066
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发表时间：
2017-12-15
影响因子：
9.9
通讯作者：
Kuroda, Yasushige
中科院分区：
文献类型：
--
作者：
Nishi, Masayasu;Ohkubo, Takahiro;Kuroda, Yasushige
纳米多孔碳可以优先从碱金属溴化物水溶液中吸附溴离子，即使是在pi-共轭表面也是如此。我们的结果表明了一种新的吸附机理，即质子的共吸附增强了阴离子在碳上的吸附。(C)2017 Elsevier Inc.保留所有权利。
Nanoporous carbons can preferentially adsorb bromide ions from an aqueous solution of alkali metal bromides, even on pi-conjugated surfaces. Our results show a new adsorption mechanism whereby coadsorption of protons enhances the adsorption of the anions onto the carbons. (C) 2017 Elsevier Inc. All rights reserved.