One-step catalytic conversion of ethanol into 1,3-butadiene using zinc-containing talc
One-step catalytic conversion of ethanol into 1,3-butadiene using zinc-containing talc
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DOI：
10.1016/j.catcom.2015.04.023
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发表时间：
2015-08
影响因子：
3.7
通讯作者：
Y. Sekiguchi;Sohta Akiyama;Wataru Urakawa;To-ru Koyama;A. Miyaji;Ken Motokura;T. Baba
中科院分区：
文献类型：
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作者：
Y. Sekiguchi;Sohta Akiyama;Wataru Urakawa;To-ru Koyama;A. Miyaji;Ken Motokura;T. Baba
与之前报道的催化剂相比，含锌滑石粉在673 K下一步转化乙醇时，1,3-丁二烯的生成率最高。结果表明，含锌量仅为1.4 wt.%的滑石以1.9 × 10−2mol g−1h−1的速率生成1,3-丁二烯。
Compared with previously reported catalysts, zinc-containing talc exhibited the highest formation rate of 1,3-butadiene in one-step conversion of ethanol at 673 K. Our results showed that talc containing just 1.4 wt.% of ZnO produced 1,3-butadiene at a rate of 1.9 × 10− 2mol g− 1h− 1.