Novel hybrid aluminium(iii)-catalen complexes as highly active catalysts for lactide polymerisation: towards industrial relevance.
Novel hybrid aluminium(iii)-catalen complexes as highly active catalysts for lactide polymerisation: towards industrial relevance.
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DOI：
10.1039/d0cc02733b
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发表时间：
2020-05
影响因子：
4.9
通讯作者：
J. Payne;P. Mckeown;G. Kociok‐Köhn;Matthew D. Jones
中科院分区：
文献类型：
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作者：
J. Payne;P. Mckeown;G. Kociok‐Köhn;Matthew D. Jones
在此，我们报道了一系列基于新型杂化配体的高活性Al(iii)-配合物：过氧化氢。在溶液条件和工业上首选的熔体条件下，演示了它们在聚乳酸生产中的应用。讨论了扩大引发剂范围的潜在结构多样化。
Herein, we report a series of highly active Al(iii)-complexes based on a novel hybrid ligand: the catalen. Their application in the production of polylactide under both solution, and industrially preferred melt conditions, is demonstrated. Potential structural diversification to broaden initiator scope is discussed.