Partial Ring-Opening and Rearrangement Reactions of P,C-Cages to Yield Unusual Phosphinous Acids Stabilized by Pentacarbonyltungsten
Partial Ring-Opening and Rearrangement Reactions of P,C-Cages to Yield Unusual Phosphinous Acids Stabilized by Pentacarbonyltungsten
复制标题
P,C-笼的部分开环和重排反应产生由五羰基钨稳定的异常亚磷酸
DOI：
10.1021/om9009334
复制
发表时间：
2010
期刊：
影响因子：
2.8
通讯作者：
R. Streubel
中科院分区：
文献类型：
--
作者：
M. Bode;G. Schnakenburg;J. Daniels;A. Marinetti;R. Streubel
报道了多环膦烷配合物3a-c的第一个反应，包括氢氧化锂诱导的部分开环和重排反应，得到新的三环次膦酸配合物4 - 7作为最终产物。除了多核核磁共振、红外光谱和质谱，配合物4 - 6的分子结构是通过单晶X射线晶体学确定的。
First reactions of polycyclic phosphirane complexes 3a−c are reported that include lithium hydroxide induced partial ring-opening and rearrangement reactions to give new tricyclic phosphinous acid complexes 4−7 as final products. Besides multinuclear NMR and IR spectroscopy and mass spectrometry, the molecular structures of complexes 4−6 were established by single-crystal X-ray crystallography.