Palladium-catalysed carbonylation of unsaturated compounds
Palladium-catalysed carbonylation of unsaturated compounds
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钯催化不饱和化合物的羰基化
DOI：
10.1016/s0020-1693(00)92491-5
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发表时间：
1969
影响因子：
2.8
通讯作者：
C. F. Kohll
中科院分区：
文献类型：
--
作者：
D. Medema;R. V. Helden;C. F. Kohll
在钯（II）/铜（II）催化剂存在下烯烃的氧化羰基化反应生成β取代和/或α-β不饱和羧酸衍生物。钯催化烯丙基化合物的羰基化反应可得到β-γ不饱和羧酸衍生物，而叔烯丙基胺可转化为γ-氨基酸.本文描述了共轭和累积的二烯与π-烯丙基钯配合物的相互作用，作为钯催化由二烯、醇和一氧化碳或由二烯合成多不饱和羧酸衍生物的一部分，烯丙基化合物与一氧化碳反应，并讨论了反应的动力学和机理。
The oxiative carbonylation of olefins in the presence of palladium(II)/copper(II) as catalyst yields β substituted and/or α-β unsaturated carboxylic acid derivatives. The palladium-catalyzed carbonylation of allylic compunds affords β-γ unsaturated carboxylic acid derivatives, while tertiary allylamines can be converted into γ-amino acids.The interaction of confugated and cumulated dienes with π-allylic palladium complexes is described as part of palladium-catalysed synthesis of polyunsaturated carboxylic acid derivatives from a diene, an alcohol and carbon monoxide or from a diene, an allylic compound and carbon monoxide.The kinetics and mechanisms of these reaction are discussed.