Organosulfonate Counteranions-A Trapped Coordination Polymer as a High-Output Triboelectric Nanogenerator Material for Self-Powered Anticorrosion
Organosulfonate Counteranions-A Trapped Coordination Polymer as a High-Output Triboelectric Nanogenerator Material for Self-Powered Anticorrosion
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有机磺酸盐抗衡阴离子-一种捕获配位聚合物作为高输出摩擦纳米发电机材料用于自供电防腐
DOI：
10.1002/chem.201904873
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发表时间：
2019
期刊：
影响因子：
--
通讯作者：
Mi Liwei
中科院分区：
文献类型：
--
作者：
Zhang Yingying;Wu Jiarui;Cui Siwen;Wei Wutao;Chen Weihua;Pang Rui;Wu Zijie;Mi Liwei
摩擦电极材料的选择对摩擦电纳米发电机（TENG）的性能至关重要。在温和的反应条件下，采用配位驱动的自组装方法合成了一种具有供电子能力的含有机磺酸盐反阴离子的金属-有机配合物，并选择该配合物作为正极材料，构建了具有高输出性能的摩擦电纳米发电机，其峰值短路电流密度为98.6 μA，输出电压为1180 V。作为实际应用，它被证明可以点亮1488个商用绿色led，并为防腐系统设备供电，以保护金属免受腐蚀。
Selection of the friction electrode materials is crucial to the performance of a triboelectric nanogenerator (TENG). In the present study, a metal–organic coordination complex containing organosulfonate counteranions with electron‐donating ability was synthesized through the coordination‐driven self‐assembly approach under mild reaction conditions and was chosen as a positive electrode material to construct a triboelectric nanogenerator, exhibiting high‐output performance with a peak value of short circuit current density of 98.6 μA and an output voltage of 1180 V. As a practical application, it was shown to light up 1488 commercial green LEDs and power an anticorrosion system device to protect metals from corrosion.