Nonmetal Catalyzed Insertion Reactions of Diazocarbonyls to Acid Derivatives in Fluorinated Alcohols
Nonmetal Catalyzed Insertion Reactions of Diazocarbonyls to Acid Derivatives in Fluorinated Alcohols
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DOI：
10.1021/ol102923h
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发表时间：
2011-02-18
期刊：
影响因子：
5.2
通讯作者：
Crousse, Benoit
中科院分区：
文献类型：
--
作者：
Dumitrescu, Lidia;Azzouzi-Zriba, Kaouther;Crousse, Benoit
在没有金属催化剂的情况下，重氮羰基与酸的插入反应可以在氟化醇中顺利进行。这种新方法允许化学选择性制备各种功能化化合物，如酰基氧酯、沉积肽、磺酸盐、膦酸盐或硼酸盐衍生物。
The insertion reaction of diazocarbonyls to acids could be performed smoothly in fluorinated alcohols in the absence of metal catalyst. This new procedure allowed the chemoselective preparation of various functionalized compounds such as acyloxyesters, depsipeptides, and sulfonate, phosphonate, or boronate derivatives.