Heterogeneously Catalyzed Synthesis of Primary Amides Directly from Primary Alcohols and Aqueous Ammonia
Heterogeneously Catalyzed Synthesis of Primary Amides Directly from Primary Alcohols and Aqueous Ammonia
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DOI：
10.1002/anie.201107110
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发表时间：
2012-01-01
影响因子：
16.6
通讯作者：
Mizuno, Noritaka
中科院分区：
文献类型：
--
作者：
Yamaguchi, Kazuya;Kobayashi, Hiroaki;Mizuno, Noritaka
在氧化锰基八面体分子筛（OMS-2）存在下，可以由伯醇和氨直接合成一系列伯酰胺。所观察到的催化剂是多相的，并且回收的催化剂可以重复使用多次而没有明显的催化性能损失。
In the presence of a manganese oxide based octahedral molecular sieve (OMS-2), a range of primary amides could be synthesized directly from primary alcohols and ammonia. The observed catalysis was heterogeneous, and the recovered catalyst could be reused many times without an appreciable loss of its catalytic performance.