Excited state properties of a short π-electron conjugated peridinin analogue.

Excited state properties of a short π-electron conjugated peridinin analogue.
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DOI:
10.1016/j.cplett.2014.01.002
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发表时间:
2014-02-11
影响因子:
2.8
通讯作者:
Frank, Harry A.
Frank, Harry A.
中科院分区:
化学4区
文献类型:
--
作者:
Magdaong, Nikki M.;Niedzwiedzki, Dariusz M.;Greco, Jordan A.;Liu, Hongbin;Yano, Koki;Kajikawa, Takayuki;Sakaguchi, Kazuhiko;Katsumura, Shigeo;Birge, Robert R.;Frank, Harry A.

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C29-peridinin is a synthetic analogue of the important, naturally-occurring carotenoid, peridinin, found in several marine algal species. C29-peridinin has five conjugated carbon-carbon double bonds compared to eight possessed by peridinin and also lacks the methyl group functionalities typically present along the polyene chain of carotenoids. These structural modifications lead to unique excited state properties and important insights regarding the factors controlling the photophysics of peridinin and other carbonyl-containing carotenoids, which are critical components of the light-harvesting systems of many photosynthetic organisms.
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