The Influence of Defects on the Electron-Transfer and Magnetic Properties of
The Influence of Defects on the Electron-Transfer and Magnetic Properties of
复制标题
缺陷对电子传递和磁性能的影响
DOI：
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发表时间：
2018
期刊：
影响因子：
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通讯作者：
P. V. Koningsbruggen
中科院分区：
文献类型：
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作者：
Esther J.M. Maccallini;Enrico Gournis;Dimitris Rudolf;P. Bakas;Thomas Luzon;Javier Broer;Henderika Pugzlys;Audrius Lummen;Tom T.A. van Loosdrecht;Paul H.M;Esther J. M. Vertelman;Enrico Maccallini;D. Gournis;P. Rudolf;T. Bakas;J. Luzón;R. Broer;A. Pugžlys;T. Lummen;P. Loosdrecht;P. V. Koningsbruggen
本文报道了化合物RbxMn [Fe（CN）zH 2 O的合成和表征。材料的组成显著地取决于所应用的制备条件。光谱结果（FTIR，拉曼，57 Fe穆斯堡尔谱，XPS）和X射线粉末衍射数据的分析产生了进一步的评估在结构特征的差异方面的Fe（CN）6空位的数量和相关的水分子的数量。各种样品的特征性个体磁性行为以及金属-金属电荷转移能力可能与结构内的显著变化有关，这些变化似乎与所使用的合成方法有关。
The synthesis and detailed characterization of a few samples of the compound Rb x Mn[Fe(CN) z H 2 O are described. The composition of the materials significantly depends on the applied preparative conditions. Analysis of spectroscopic results (FTIR, Raman, 57 Fe Mo¨ssbauer, XPS) and X-ray powder-diffraction data yielded a further assessment of the difference in structural features in terms of the amount of Fe(CN) 6 vacancies and the associated number of water molecules. The characteristic individual magnetic behavior, as well as the metal-to-metal charge-transfer capabilities of the various samples, could be related to significant changes within the structures that appear to be associated with the synthetic method used.