Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3
Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3
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DOI：
10.1039/c1cc10438a
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发表时间：
2011-01-01
影响因子：
4.9
通讯作者：
Stephan, Douglas W.
中科院分区：
文献类型：
--
作者：
Heiden, Zachariah M.;Stephan, Douglas W.
在 H-2 下，催化量的 B(C6F5)(3) 对手性酮亚胺进行还原，产生中等至优异的非对映选择性。对于樟脑和薄荷酮衍生的亚胺，还原反应的非对映选择性大于 95%。
Reductions of chiral ketimines effected under H-2 by catalytic amounts of B(C6F5)(3) result in moderate to excellent diastereoselectivities. In the case of camphor and menthone derived imines, the reductions proceeded with greater than 95% diastereoselectivity.