A 1:1 intercluster compound consisting of +6 and -6 charged RhIII4ZnII4 octanuclear cations and anions with aminothiolate ligands
A 1:1 intercluster compound consisting of +6 and -6 charged RhIII4ZnII4 octanuclear cations and anions with aminothiolate ligands
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由 6 个和 -6 个带电 RhIII4ZnII4 八核阳离子和阴离子以及氨基硫醇配体组成的 1:1 簇间化合物
DOI：
10.1039/c3ce41800f
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发表时间：
2013
期刊：
影响因子：
3.1
通讯作者：
Ukyo Yamashita and Takumi Konno
中科院分区：
文献类型：
--
作者：
Nobuto Yoshinari;Ukyo Yamashita and Takumi Konno
第一个例子是由[Zn4O {Rh（aet）3} 4] 6+（aet = 2-氨基乙硫醇盐）和[Zn4O {Rh（L-cys）3} 4] 6 −（L-cys = L-半胱氨酸盐）合成的具有+6电荷阳离子和-6电荷阴离子的1：1金属-有机簇间化合物。 其结构由单晶X射线晶体学确定，其揭示了簇阴离子的类金刚石（diamondoid）氢键网络的形成，在其空腔中容纳簇阳离子。
The first example of a 1 : 1 metal–organic intercluster compound with +6 charged cations and −6 charged anions was synthesized from [Zn4O{Rh(aet)3}4]6+ (aet = 2-aminoethanethiolate) and [Zn4O{Rh(L-cys)3}4]6− (L-cys = L-cysteinate). Its structure was determined by single-crystal X-ray crystallography, which revealed the formation of a diamondoid (dia) hydrogen-bonding network of the cluster anions, accommodating the cluster cations in its cavities.