Construction of tetralin skeletons based on rhodium-catalysed site-selective ring opening of benzocyclobutenols
Construction of tetralin skeletons based on rhodium-catalysed site-selective ring opening of benzocyclobutenols
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DOI：
10.1039/c4cc09327e
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发表时间：
2015-01-01
影响因子：
4.9
通讯作者：
Murakami, Masahiro
中科院分区：
文献类型：
--
作者：
Ishida, Naoki;Ishikawa, Norikazu;Murakami, Masahiro
四氢化萘（四氢萘）是由苯并环丁烯醇合成的，基于铑催化的位点选择性开环，然后将所得芳基铑物质与缺电子烯烃进行分子间/分子内共轭加成。所产生的结构与在热反应条件下由相同化合物获得的结构形成了显着的对比。
Tetralins (tetrahydronaphthalenes) are synthesised from benzocyclo-butenols based on the rhodium-catalysed site-selective ring opening followed by intermolecular/intramolecular conjugate addition of the resulting arylrhodium species to electron-deficient alkenes. The produced structures make a remarkable contrast with those available from the same compounds under thermal reaction conditions.