X-ray Crystal Structures of Discrete and Polymeric Silver Based Molecules Containing 4,4′-Dimethyl-2,2′-Bipyridine and 2,2′-Bipyridine
X-ray Crystal Structures of Discrete and Polymeric Silver Based Molecules Containing 4,4′-Dimethyl-2,2′-Bipyridine and 2,2′-Bipyridine
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DOI：
10.1007/s10870-008-9499-3
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发表时间：
2009-06-01
影响因子：
0.8
通讯作者：
Klausmeyer, Kevin K.
中科院分区：
文献类型：
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作者：
Hung-Low, Fernando;Renz, Amanda;Klausmeyer, Kevin K.
AgBF_4与4，4 ′-二甲基-2，2 ′-联吡啶和2，2 ′-联吡啶反应，得到三种未见报道的化合物。通过单晶X-射线衍射测定了这些化合物的分子结构。1的结晶发生在中心对称单斜空间群C2/c（No.15）中，其中a = 23.407（3），B = 10.7552（13），c = 13.9332（17）;和β = 111.893（2）和Z = 8。2的结晶发生在中心对称的正交晶系空间群Pbca（No.61）中，其中a = 11.178（3），B = 23.590（6），c = 29.339（8）和Z = 8。3的结晶发生在中心对称单斜空间群P2（1）/c（No.14）中，其中a = 11.2250（6），B = 8.7713（5），c = 15.4048（8），β = 109.333（2），Z = 4。详细的标题化合物的合成和结构表征的介绍和讨论。
The reaction of AgBF4 with 4,4'-dimethyl-2,2'-bipyridine and 2,2'-bipyridine yields three previously unreported compounds. The molecular structures of these compounds were obtained by single-crystal X-ray diffraction. Crystallization of 1 occurs in the centrosymmetric monoclinic space group C2/c (No. 15) with a = 23.407(3), b = 10.7552(13), c = 13.9332(17); and beta = 111.893(2) and Z = 8. Crystallization of 2 occurs in the centrosymmetric orthorhombic space group Pbca (No. 61) with a = 11.178(3), b = 23.590(6), c = 29.339(8) and Z = 8. Crystallization of 3 occurs in the centrosymmetric monoclinic space group P2(1)/c (No. 14) with a = 11.2250(6), b = 8.7713(5), c = 15.4048(8), and beta = 109.333(2) and Z = 4. Details of the synthesis and the structural characterization of the title compounds are presented and discussed.