Catalytic asymmetric S-H insertion reaction of carbenoids
Catalytic asymmetric S-H insertion reaction of carbenoids
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DOI：
10.3998/ark.5550190.0004.210
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发表时间：
2003-02
期刊：
影响因子：
0.9
通讯作者：
Xiaomei Zhang;M. Ma;J. Wang
中科院分区：
文献类型：
--
作者：
Xiaomei Zhang;M. Ma;J. Wang
用手性Rh（II）和Cu(I)催化剂研究了芳基重氮乙酸酯生成的类碳化合物的不对称S-H插入。手性Rh（II）催化剂对ee的选择性为12% ~ 23%。
Catalytic asymmetric S-H insertion of carbenoids generated from aryldiazoacetates has been investigated with a number of chiral Rh(II) and Cu(I) catalysts. 12 % - 23 % ee enantioselectivity were achieved with chiral Rh(II) catalysts.