Significant enhancement of gas uptake capacity and selectivity via the judicious increase of open metal sites and Lewis basic sites within two polyhedron-based metal-organic frameworks
Significant enhancement of gas uptake capacity and selectivity via the judicious increase of open metal sites and Lewis basic sites within two polyhedron-based metal-organic frameworks
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通过在两个基于多面体的金属有机框架内明智地增加开放金属位点和路易斯碱性位点，显着增强气体吸收能力和选择性
DOI：
10.1039/c5cc09922f
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发表时间：
2016
影响因子：
4.9
通讯作者：
Liu Yunling
中科院分区：
文献类型：
--
作者：
Liu Bing;Yao Shuo;Shi Chao;Li Guanghua;Huo Qisheng;Liu Yunling
Two new isomorphous polyhedron-based MOFs (JLU-Liu20 and JLU-Liu21), with dual functionalities of OMSs and LBSs, have been synthesized by using the SBB strategy. By judiciously avoiding the DABCO axial ligand, JLU-Liu21 possesses more OMSs than JLU-Liu20, and exhibits a significant enhancement of CO2 uptake capacity 210 versus 162 cm3 g−1 for JLU-Liu20 at 273 K under 1 bar.
