Preparation of dithioesters from alkynethiolates and thiols: Evidence for the intermediate occurrence of thioketenes

Preparation of dithioesters from alkynethiolates and thiols: Evidence for the intermediate occurrence of thioketenes
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从炔硫醇和硫醇制备二硫酯:硫烯酮中间存在的证据

DOI:
10.1002/recl.19660850906
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发表时间:
2010
期刊:
Recueil des Travaux Chimiques des Pays-Bas
影响因子:
--
通讯作者:
J. F. Arens
J. F. Arens
中科院分区:
--
文献类型:
--
作者:
P. Schuijl;L. Brandsma;J. F. Arens

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Dithioesters
Dithioesters have been obtained in satisfactory yields by adding ethereal solutions of lithium alkynethiolates, RCCSLi, to an excess of a thiol. Thioketenes RCHCS are supposed to be intermediate species.