One-dimensional water cages with repeat units of (H2O)24 resembling pagodane trapped in a 3D coordination polymer: proton conduction and tunable luminescence emission by adsorption of anionic dyes

One-dimensional water cages with repeat units of (H2O)24 resembling pagodane trapped in a 3D coordination polymer: proton conduction and tunable luminescence emission by adsorption of anionic dyes
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DOI:
10.1039/c5ce00969c
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发表时间:
2015-06
期刊:
影响因子:
3.1
通讯作者:
Kartik Maity;T. Kundu;R. Banerjee;K. Biradha
Kartik Maity;T. Kundu;R. Banerjee;K. Biradha
中科院分区:
化学3区
文献类型:
--
作者:
Kartik Maity;T. Kundu;R. Banerjee;K. Biradha

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一个三维配位聚合物被证明可以捕获由重复单元(H2O)24组成的一维多面体水笼,其几何形状类似于外来的有机分子pagodane。此外,该材料通过吸附阴离子染料如荧光素二价阴离子而表现出质子传导能力和可调发光。
A 3D-coordination polymer was shown to trap one-dimensional polyhedral water cages consisting of repeat units of (H2O)24, the geometry of which resembles the exotic organic molecule pagodane. Further, this material exhibited proton conduction ability and tunable luminescence emission by adsorption of anionic dyes such as the fluorescein dianion.